This is one of the few times when looking at SMBv2 you will need to use SMBv1 commands. The initial negotiation request will always be sent out as SMBv1. It makes sense when you think about it, SMB does not have ‘backwards compatibility’, instead it relies on negotiating to the lowest common denominator.
To find the initial request use the following SMBv1 command
smb.cmd == 0x72
If the server responds using the SMB2 protocol a second negotiation is sent. This time on SMB2.
To see all SMB2 negotiation and responses you will need the following command
smb2.cmd == 0
During the negotiation you are able to see what capabilities the server has, what the client has and any negotiated authentication/encryption technique. You can also see the time that is set on the server, as well as its Timezone.
Why do I care?
There is a lot of useful information in here to help with Server identification and potentially geographical location. Looking at the capabilities of the server can with OS identification; is it a Windows box, a NAS etc.
Using the SMBv1 filter you are able to see the first communication between the two devices, aiding in timeline building.